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HETEROCHEMISTRY AND ASYMMETRIC SYNTHESIS

HSA
1.5
8
HETEROCHEMISTRY AND ASYMMETRIC SYNTHESIS
french

21h

Organic chemistry course, approaching the properties and synthesis of compounds comprising Phosphorus, Sulfur and Silicon atoms.Several important reactions of organic chemistry are approached (Wittig, Staudinger, Mitsunobu, Swern, Peterson...). The second part is dedicated to enantioselective synthesis bases.

  1. Heteroaromatic chemistry
  • Generalities about hetero compounds
  • Organophosphorus : structure, preparation technique and reactivity
  • Organosilicon compound : structure, preparation technique and reactivity
  • Organosulfur compound : structure, preparation technique and reactivity
  1. Enantioselective synthesis basis
  • Reminder of the different types of chirality
  • Notions of asymetric induction
  • Method of enantiomeric excess determination.
  • Simple examples of diastereoselective methods

One end of semester final exam 3h

 

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